NSUF 18-1589: Irradiation Damage in (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C High-Entropy Ceramics

The objective of this project is examine the irradiation damage behavior in the novel high-entropy ceramics (HEC) as the potential candidate materials for the extreme environments in next-generation nuclear energy systems. A novel high-entropy carbide ceramic, (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C, with a single-phase rock salt structure, has been recently developed in the PI’s lab. To our knowledge, there has been no report on the irradiation damage behavior in HEC. The hypothesis is that HECs such as (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C have higher irradiation tolerance than binary carbide ceramics (such as ZrC, HfC), because the significant chemical disorder and lattice distortion can slow energy dissipation and suppress formation of irradiation defects. This proposed work will investigate (i) helium irradiation induced bubbles and defect clusters in (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C at 800 °C to ~5 dpa, and (ii) heavy ion irradiation induced defect clusters at room temperature and 800 °C to ~20 dpa. The scientific outcome will be the fundamental knowledge of irradiation resistance of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C in terms of microstructure stability with insights into the nature and type of irradiation defects in this novel material. This will help predict the in-service degradation of HEC in advanced nuclear reactor environments such as VHTR and GFR, in which ceramic materials are being actively pursued as fuel cladding materials

Допълнителна информация

Поле Стойност
Awarded Institution University of Nebraska-Lincoln
Embargo End Date 2020-06-17
Facility Tech Lead Alina Montrose, Lin Shao, Mukesh Bachhav
NSUF Call FY 2018 RTE 3rd Call
PI Bai Cui
Project Member Professor Lin Shao, Professor - Texas A&M University (https://orcid.org/0000-0002-5703-1153)
Project Member Professor Bai Cui, Professor - University of Nebraska-Lincoln (https://orcid.org/0000-0002-0585-6698)
Project Member Dr. Cheng Sun, Associate Professor - Clemson University (https://orcid.org/0000-0003-4104-8898)
Project Notes Awarded on 09/17/2018
Project Type RTE
Publication High-Entropy Carbide Ceramics for Extreme Environments Bai Cui Materials Science & Technology 2019 2019-09-29 - 2019-10-03
Publication Irradiation Damage Behavior in Novel High-Entropy Carbide Ceramics Bai Cui ANS Annual Meeting 2019-06-09 - 2019-06-13
Publication Irradiation Damage Behavior in Novel High-Entropy Carbide Ceramics Bai Cui, Lin Shao, Michael Nastasi Transactions of the American Nuclear Society 120 2019-06-13 https://ncesr.unl.edu/wordpress/wp-content/uploads/2019/08/Irradiation-Damage-Behavior-in-Novel-High-Entropy-Carbide-Ceramics.pdf
Publication Irradiation Damage Behavior in Novel High-Entropy Carbide Ceramics Transactions of the American Nuclear Society 120 https://ncesr.unl.edu/wordpress/wp-content/uploads/2019/08/Irradiation-Damage-Behavior-in-Novel-High-Entropy-Carbide-Ceramics.pdf
Publication Irradiation damage in (Zr0.25Ta0.25Nb0.25Ti0.25)C high-entropy carbide ceramics Bai Cui, Lin Shao, Yaqiao Wu Acta Materialia None 2020-06-12 https://www.sciencedirect.com/science/article/abs/pii/S1359645420304353
RTE Number 1589